Hi Rich and Jeff,
As far as I know, the
real chemical cause of wool degradation («corrosion») in presence of
mordants like iron-, copper-, or tin salts has not been sufficiently
analysed.
Not even the most frequent case, the corrosion of iron /
tannin black- and brown-shades, has yet received a convincing explanation.
A fortiori, we ignore the reasons of the potential negative effects of
tin (for brighter reds, with cochineal and/or madder ) or copper (for pale
almond greens, with various natural yellows).
It appears that wool
degradation is not a fatality though. A perfect rinsing of a tin-mordanted
red or of a copper-mordanted green seems (in my limited experience)
sufficient for avoiding "corrosion" problems. And the concentration of the
mordant plays a role too, a fact which the seventeenth- and eighteenth
century dyers knew very well, as shown by their recipes for iron / tannin
black shades. Very small concentrations of copper in an alum/copper mix of
mordants can even improve the lightfastness of the dyeing with some
natural yellows.
I do not know whether copper-based pale greens
were indeed used by weavers of oriental carpets, nor where or when that
may have happened. However, given the ubiquity in central Asia of copper-
and tinned copper vessels (and the easy oxidation of both metals), it
would seem quite unlikely that the dyers would not have discovered by
accident the possibilities of new shades created by these
mordants.
True Rich, many copper salts are blue or green (copper
acetate, sulfate and carbonate for example) but this fact is unrelated to
the shade of the various metal complexes formed between the copper atom
and the various natural yellow dyes in mordant dyeing.
Besides, most
such mordant dyeing operations involving copper and a yellow natural dye
actually yield a brown or a greenish-brown. A pale green shade is rather
the exception.
Not only copper but also iron allows to achieve
various pale greens with natural yellows. It all depends on the relative
concentrations of the various mordants (Alum, copper, iron).
Two examples, among many possible:
A. Wool pre-mordanted
with alum and little copper, with Reseda luteola
B. Wool pre-mordanted
with alum and little iron, with Matricaria chamomila
best
regards
Pierre